Apparatus for upgrading liquid hydrocarbons

ABSTRACT

Apparatus for the treatment of a liquid hydrocarbon charge containing solids or solids-forming contaminants, e.g., inorganic solids, metals and asphaltenes, which includes a contactor vessel having a liquid charge inlet, a vaporizing media inlet above the charge inlet and a vapor-solids outlet. An atomizer is positioned in the charge inlet for forming small particles of the liquid charge and directing the particles of liquid in a substantially horizontal flat pattern into the contactor vessel. A premix downcomer having a dispersion grid positioned therein is located in the vaporizing media inlet for introducing a fluidized mixture of a gas dispersion media and hot circulating solid particles into the contactor vessel in a substantially vertical flat pattern to traverse the path of the liquid particles and intimately contact the liquid particles. The vapor-solids-outlet is positioned in the contactor vessel substantially opposite the liquid charge inlet to receive product vapors and entrain solid particles and rapidly pass the same into cyclones connected to the vapor-solids-outlet for separating solid particles from product vapors. A stripper vessel is located beneath the contactor vessel for receiving heavy solid particles and stripping hydrocarbons therefrom.

This is a division of application Ser. No. 116,886, filed Nov. 5, 1987,now U.S. Pat. No. 4,859,315.

This invention relates to a process and apparatus for separating solidsor solids-forming contaminants from a liquid to be upgraded. Moreparticularly, it relates to such a process and apparatus for theupgrading of heavy, liquid hydrocarbon charge-stocks, such as petroleumor fractions thereof, and tar sand bitumens by reducing the content ofcoke precursors, metal compounds, inorganic solids, and the like tofacilitate further processing of such charge-stocks.

BACKGROUND OF THE INVENTION

It is well known that many petroleum crudes, and heavy fractions thereofsuch as atmospheric or vacuum resides (the residue remaining afterfractional distillation of crude oil to remove lighter components)contain coke precursors and metal compounds in amounts which adverselyaffect further down-stream processing and also, affect the quality ofheavy fuels produced therefrom. Similarly, it is known that bitumensobtained from tar sands and heavy oil deposits are difficult andexpensive to process because of their high content of asphaltenes anddifficult to remove fine particles of inorganic solids.

The above-mentioned coke precursors include polyacrylic hydrocarbons,asphaltenes and the like which tend to break down at elevatedtemperatures to form carbonaceous materials, often referred to as"coke." In subsequent processing coke may form on the interior walls ofrefining equipment or be deposited on catalyst to reduce its activitylevel. Hence, a feed-stock with a high coke forming tendency isundesirable. The coke forming tendency of an oil is generally evaluatedby the Conradson Carbon method or the Ramsbottom Carbon method. A highernumber from such an evaluation indicates a greater tendency for cokedeposition on, for example, catalyst when the oil is processed by thefluid catalytic cracking (FCC) process wherein gas oils are cracked toproduce gasoline and other lighter products. In the FCC process, coke isburned from the catalyst in a regenerator to restore catalyst activityand the regenerated catalyst is then recycled for the cracking ofadditional feed-stock.

The above-mentioned heavy oil charge-stocks often contain compounds ofundesirable metals, including nickel and vanadium, which when depositedon FCC catalyst may adversely affect the physical properties of thecatalyst and also promote the undesirable production of coke, hydrogrenand other light hydrocarbon gases in the operation of the FCC process.

Similarly, the bitumen from tar sands contains minute, sometimescolloidal, particles of sand which, because of the difficulty ofremoval, cause processing problems in down-stream processing. Also heavyoil deposits often contain fine particles of solids, such as diatomite,which cause similar problems. Although there are vast deposits of suchhydrocarbons, their development has been retarded because of the highcost of obtaining and processing synthetic crudes (syncrudes) from suchdeposits and problems caused by the high content of solids andasphaltenes.

The oil refining industry has long been plagued with the problem ofmaximizing high value transportation fuels (e.g., gasoline, jet, anddiesel fuels) while minimizing the lower value fuel oil, especiallyresidual oil, which is usually high in sulfur and metals. These heavyfuel oils, which are the heavy end of the crude oil, often requirefurther upgrading to decrease the sulfur and metal contents.

The original oil refinery was a very simple bach distillation device inwhich crude oil was heated to separate the lighter more valuableproducts of naphtha and kerosene. It was discovered that further heatingof the oil that was left after distillation of the lighter products ofnaphtha and kerosene from the crude oil would result in increased yieldof lighter products. However, these additional products did not have thesame characteristics as the naturally occurring (virgin) material in thecrude oil and were considered "wild" and "unstable" and thereforeundesirable. This discovery was what is now referred to as thermalcracking which was used for years as a method of decreasing the bottomof the barrel. As time progressed, the thermal cracking technology wasrelegated to the upgrading of the absolute bottom of the barrel or"vacuum bottoms." The virgin material in the crude which was heavierthan kerosene or diesel but lighter than vacuum bottoms is nowpredominantly upgraded by the fluid catalytic cracking process (FCC).

In order to produce the feed-stocks for the units in the refinery thesimple batch distillation system was replaced with continuousdistillation which consisted of a crude unit followed by a vacuum unit.Thus, this resulted in two distillation systems, both containing almostthe same equipment of a charge heater, exchangers, and a distillationcolumn. Both systems were required because the heavy atmospheric towerbottoms would thermally crack if a vacuum was not applied to the systemto permit the separation to take place at a lower temperature. Therefining industry is still trying to reduce the vacuum bottoms yield,but is limited by the equipment employed. This limit is imposed by thetime-temperature relationship of the feed heaters. Normally one islimited to about 750 degrees F. on the outlet of the heater. Above thistemperature thermal cracking will take place in the heater coils becauseof high temperatures and time. This thermal cracking results in cokingof the heater tubes, overloading of the vacuum ejectors, and "unstable"products.

These processing limitations plus the decreasing availability of lightercrudes, are putting pressure on the industry to find acceptable methodsto upgrade the vacuum bottoms. There are many technically feasibleprocesses, but the economics are far from optimum. The hydrogen additionprocesses require high pressures and large volumes of catalyst, whichresult in high capital investments, high operating costs, and catalystdisposal problems. The carbon rejection processes are basically lesscapital intensive, but result in degraded products which need to befurther treated, and therefore, increase the capital investment. Thesecarbon rejection processes also produce undesirable byproducts such ashigh sulfur and high metals coke or, if they use a circulating solid,present a large catalyst disposal problem.

Many techniques are known for upgrading such hydrocarbon charge stockscontaminated with the above-described solids and solid-formingcontaminants. For example, delayed and fluid coking processes are used.The coking process uses thermal conversion to produce coke and cokergasoline, coker gas oil, etc. The solid coke is usually high in ash andsulfur, and the distillate often must be further treated before it canbe used for charging to catalytic cracking or blending. Solventextraction and deasphalting processes also are used for preparing FCCcharge-stocks from resids.

In U.S. Pat. No. 4,263,128, I have disclosed a process for upgradingwhole crude and bottoms fractions from distillation of petroleum by hightemperature, short time contact with a fluidizable solid of essentiallycatalytically inert character to deposit high boiling components of thecharge stocks on the circulating solid, whereby Conradsen Carbon values,salt content and metal content are reduced. Therein, an inert solid,such as particles of kaolin clay, is supplied to a rising column for thecharge in a contactor to vaporize most of the charge. Carbonaceous andmetallic deposits formed on the particles of circulating solid areburned, after which the solid particles are recycled to the contactor.

In U.S. Pat. No. 4,435,272, I have disclosed a process for upgradingsuch charge-stocks by dispersing the charge introduced into a contactorinto a descending curtain of heated particles of an added inert-contactmaterial. The charge is vaporized and carbonaceous materials, salt andmetals are deposited on the circulating contact material. Deposits onthe contact material are then burned off, the heat of combustion isabsorbed by the contact material and the heated contact material isrecycled to the contactor for vaporizing the charge.

It is also known to spray FCC feed into a riser reactor of a catalyticcracking unit to improve contact between the feed and catalyst.

Such known processes permit increased utilization of the crude (orsyncrude) to produce transportation fuels, but they have high capitaland operating costs and may crease environmental concerns.

Therefore, a primary object of the present invention is to reduce thecapital and operating costs of the typical refinery. It is a furtherobject to minimize the environmental concerns while allowing the typicalrefiner to increase transportation fuels yield on crude and to eliminateor reduce the heavy fuel oil yield. These objects may be accomplished byusing the process and apparatus of the present invention in place of thecrude and vacuum units.

The present invention permits minimizing the degree of thermal crackingso that the products can be treated in existing downstream equipment.Further, the present invention makes it possible to eliminate the vacuumbottoms processing problems by removing over 95% of the metals and over95% of the asphaltenes, and reducing the sulfur and nitrogen in thefeedstock by 30 to 80% while at the same time removing any solids in thefeedstock. This latter point is especially important in the upgrading oftar sands bitumens. Transportation fuel yields of 90% or more may beachieved, while the yield of heavy fuel oil may be reduced to 4% or lessby use of the present invention. The virtual elimination of the catalystpoisons of metals and asphaltenes allows for the upgrading of the heavyoil product from this process in conventional downstream equipment suchas fluid catalytic cracking, or gas oil hydrotreaters or hydrocrackers.

Additional objects and advantages of the present invention will be setforth in part in the following description and in part will be obviousfrom the description, or may be learned by practice of the invention.The objects and advantages of the invention may be realized and obtainedby means of the instrumentalities and combinations particularly pointedout in the appended claims.

SUMMARY OF THE INVENTION

To achieve the objects and in accordance with the purpose of the presentinvention, there is provided a novel continuous fluidized process forupgrading a heavy liquid hydrocarbon charge-stock or feed containingsolid or solid-forming contaminants, which process comprises atomizingthe feed to provide a stream of liquid particles (including thecontaminants), the liquid particles being of a pre-selected size. Theatomized feed is introduced substantially horizontally into a contactingzone and a stream of hot fluidized vaporizing media containing heatedsolid particles solely derived from the contaminants in the feed isintroduced substantially vertically into the contacting zone tointimately contact the atomized feed therein. The temperature of thefluidized vaporizing media and the contact time with the atomized feedtherein are sufficient to vaporize hydrocarbons in the feed. Nosubstantial cracking occurs in the contacting zone. Carbonaceousmaterial and other solids are deposited on the heated solid particles orform new solid particles. A substantial portion of the hydrocarbons arevaporized and a mixture is formed of the solid particles entrained inthe resulting vaporized hydrocarbons. The mixture is rapidly passed intoa separation zone and solid particles separated from the vaporizedhydrocarbons therein. Separated solid particles are heated to raise thetemperature of the solid particles to a temperature higher than thetemperature at which the vaporization occurs. The heated solid particlesare recycled to the contacting zone to transfer heat to the atomizedfeed, and the separated hydrocarbon vapors are condensed and ahydrocarbon product having a substantially reduced content ofcontaminants is recovered.

Typically, the hydrocarbon feed contains asphaltenes that formcarbonaceous materials which under the conditions in the contacting zoneeither are deposited on solid particles or form solid particles, orboth, in the contacting zone. The carbonaceous materials associated withthe separated solid particles are burned in a combustor, and theresulting heat of combustion heats the solid particles recycled to thecontacting zone to provide heat for the hydrocarbon vaporization.Further, the separated solid particles can be heated with hot solidparticles from the combustor, and volatile hydrocarbons strippedtherefrom prior to burning the carbonaceous materials.

Advantageously, all of the carbonaceous material formed in thecontacting zone is burned in the combustor, and further, the total heatrequired to vaporize the hydrocarbons in the contacting zone is suppliedby the recycled hot solid particles.

It is preferred that the temperature in the contacting zone and thecontact time of the hot solid particles and the vaporized feed arecontrolled to maintain the conversion of 900° F. minus material in thecharge-stock at not greater than 10%.

It is further preferred that such contact time is not greater than 5seconds, the temperature in the contacting step is greater than the meanaverage boiling point of the liquid feed and less than 1100° F. and thepressure in the contacting step is between about 10 and 50 psia.

In the practice of the preferred process, atomized charge-stock isintroduced into the contacting zone through at least one charge or feedinjector to provide a generally flat, horizontal pattern of atomizedfeed therein and the fluidized vaporizing media is introduced downwardlyinto the contacting zone in a falling curtain, or generally flatvertical pattern, to traverse said feed pattern at an angle ofapproximately 90°. The mixture of solid particles entrained in vaporizedhydrocarbons is then passed substantially horizontally to the inlet of aseparation zone which is positioned substantially opposite the point ofintroduction of the atomized feed.

The present invention also provides novel apparatus for the treatment ofa hydrocarbon liquid feed containing solids or solids-formingcontaminants comprising a contactor vessel having at least one liquidcharge or feed inlet, at least one vaporizing media inlet and at leastone vapor-solids outlet, wherein atomizing means are positioned in thecharge inlet for forming small particles of the liquid feed having apreselected size and directing the particles of liquid in asubstantially horizontal flat pattern into the contactor. Vaporizingmedia introduction means are positioned in the vaporizing media inletfor introducing a fluidized mixture of a gas dispersion media and hotcirculating solid particles into the contactor in a substantiallyvertical flat pattern so as to traverse the path of said liquidparticles and intimately contact the liquid particles. Separator meansare connected to the vapor-solids outlet for separating solid particlesentrained in vapors formed in the contactor, and the vapor-solids outletis positioned in the contactor substantially opposite the liquid feedinlet to receive the vapors and entrained solid particles and pass thesame into the separator means, so that there is a very short contacttime between the vapors and solid particles.

The separating means typically includes one or more primary cyclonesand, preferably, one or more secondary cyclones for separating vaporsand entrained particles, as is well known in the art.

The apparatus further includes a stripper vessel in flow communicationwith the contactor vessel for receiving solid particles from thecontactor and stripping hydrocarbons from the solid particles therefrom.

Further, there is included a combustor vessel in flow communication withthe stripper vessel for receiving stripped solid particles therefrom andburning carbonaceous material from the stripped solid particles,together with particle recycle means for recycling heated solidparticles from the combustor to the contactor.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic diagram illustrating a preferred system for thepractice of the present invention; and

FIG. 2 is an enlarged partial view of the system of FIG. 1 showing ingreater detail the operation of the horizontal contactor used in thepractice of the present invention.

DESCRIPTION OF PREFERRED EMBODIMENTS

Reference will now be made in detail to the present preferred embodimentof the invention, an example of which is illustrated in the accompanyingdrawings.

A system for practicing the invention is illustrated in FIG. 1. The twomajor vessels are a combustor 4 and a stripper-heater 6. A hotvaporizing media, which is described below, flows down a verticalstandpipe 8 through a slide valve 10 into a pre-mix downcomer 18. Slidevalve 10 controls the flow rate of vaporizing media to maintain thedesired temperature on a temperature controller 12 positioned in theoutlet of a high efficiency cyclone 14. Downstream of slide valve 10,the hot vaporizing media is mixed with a dispersion media, such as steamor recycle gas, from conduit 16 connected to a product distillation andrecovery section (not shown) and together with the dispersion mediaenters the premix downcomer 18 on flow control. When the temperature inthe outlet of cyclone 14 varies from a set temperature, temperaturecontroller 12 causes a signal to be sent to an operator on valve 10which adjusts the opening therein to increase or decrease the flow rateof the vaporizing media, as required. The dispersion media from conduit16 serves two purposes in that it distributes and propels the vaporizingmedia downward and acts to reduce the hydrocarbon partial pressure ofthe system.

The vaporizing media is comprised of hot particles of finely dividedsolids which are formed from the solid and solid-forming contaminants,such as asphaltenes, sand and the like in the charge-stock. Suchparticles are formed when the hydrocarbons in the charge stock arevaporized, leaving agglomerated particles of carbonaceous material (orcoke), metals or sand, or a combination thereof, either as newly-formedparticles or deposited on similar existing particles circulated in thesystem. The size of such particles will, typically, be in the range of 1to 120 microns such that they can be fluidized in the system.

Temperature override 20 is a unique feature of the control system. Thiscomprises a temperature sensing element and a flow measurement devicepositioned in the premix downcomer 18 and connected to a computer 21(FIG. 2) which is also connected to an operator on feed valve 24. Thflow rate of the charge stock in conduit 22 is determined by use of aflow measurement device 25. The computer will compute, from the flowrate and temperature of the vaporizing media and the flow rate ofcharge-stock in conduit 22, whether there is enough heat available tovaporize the feed. If there is not, the computer 21 will reset the flowrate of charge-stock to the system to a lower rate. Upon loss of thevaporizing media, the computer will shut off the feed valve 24. This isone of the features of this process system which will eliminate thepossibility of coking of the system, which would result in a shutdown.Downstream of temperature override 20, the charge-stock is atomized andinjected horizontally into a contactor 26 in intimate contact with thedispersion media and vaporizing media.

It is important that the charge-stock be atomized into the contactor 26to insure intimate contact of the charge and fluidized particles so thatthe majority of the particles, along with the dispersion media and thevaporized charge, are entrained through the horizontal contactor 26 intothe separator means which includes first and second stage cyclones 28and 14. This can be accomplished many ways, but will be described byreference to a preferred design of a horizontal contactor 26 and anatomizing means 32.

The horizontal contactor 26 comprises a substantially horizontal conduitconnecting a "top-hat" portion 33 (i.e., the upper portion ofstripper-heater 6 having a lesser diameter) of stripper-heater 6 to theinlet of first-stage cyclone 28, which is positioned opposite anatomizing means 32. The top hat 33 and horizontal contactor 26 provide acontacting zone 27 wherein the atomized charge is in intimate contactwith the heated vaporizing media. It is necessary that the atomizedcharge be introduced essentially horizontally into the top hat so as topass through a falling curtain of solid particles into contactor 26.This allows for design of the system with multiple contactors 26 andeven multiple charge injectors spaced around the particle inlet 30 intothe contactor 26. The charge injection point is essentially at orslightly higher than the center of the horizontal contactor 26 particlesinlet 30 into the top hat portion 33 of stripper-heater 6. The top hat33 is employed in this design to decrease the time in this section andwill result in a downward velocity of greater than 10 fps, and morepreferably, greater than 20 fps. The vaporized charge plus thedispersion media and majority of the solid vaporizing media willimmediately exit contactor particle inlet 30 of the stripper-heatervessel 6 through horizontal contactor 26. Horizontal contactor 26 willaccelerate the velocity of the solids and vapors up to 50 to 100 fps,depending on the cyclones employed. The time in this contactor willtypically be less than 0.1 second as the length of this contactor onlyhas to be sufficient to mechanically install cyclone 28. The heaviersolid vaporizing media and the unvaporized charge material willessentially be propelled into the top of stripper-heater 6 and heaviersolid vaporizing media will settle by gravity as fluidizable particles.These new particles will mix with the other particles entering thestripper-heater 6.

As stated previously, the proper design of the charge atomization meansto form fluidizable particles and the design of the feed-hot circulatingsolids contacting is critical. A larger view of this system is shown inFIG. 2. For purposes of description, the charge stock will be a tarsands bitumen with 10 weight percent solids. To simplify thedescription, only one feed injector and one horizontal contactor will bedescribed, but this should be in no way limiting, as those skilled inthe art will know how to add more contactors 26 and charge injectors 32for increased charging rates.

The type of charge atomizer 32 will depend to a great extent on thesolids content of the charge-stock. However, the intent is to atomizethe charge into droplets of particle size in the range of 1 to 100microns, or heavier if so desired from a fluidization point of view, toyield a circulating inventory of 40 to 90 micron average particle size.Droplets in the 1 to 10 micron average particle size range arepreferred. As stated previously, the charge stock can be atomized withwater, steam, or gas. The preferred atomizing media is gas andpreferably the same gas as used as the dispersion media. The pressuredrop across the charge stock atomizer 32 will vary from 0.5 to 30 psidepending on the solids content of the feed and the desired droplet sizeand atomizing media. The higher the solids content the lower thepressure drop to reduce erosion.

The preferred atomizing means includes an injector having a nozzle forproducinhg a flat horizontal pattern, a conduit for connection to asource of gaseous atomizing media supplied under pressure to theinjector and a conduit for supplying charge stock to the injector.

With the above in mind, the description of using a tar sands bitumenfeed with 10 weight percent solids will continue. There is no limit,except economical, on the concentration of solids in the charge that theprocess can handle. All that is ncessary is to design the system so asto recover and remove the solids, e.g., sand and metals, for disposal.As shown in FIG. 2, the charge is combined with gaseous atomizing mediafrom conduit 34, which is connected to dispersion media conduit 16, infeed injector 32, which is removable/adjustable burner assembly similarto the one typically used for injecting torch oil into a FCCregenerator. The tip of the nozzle on feed injector 32 is a horizontalslot, which will give a horizontal flat fan-shaped pattern covering anangle approximately equal to the width of the below-described fallingcurtain of hot fluidizing solid minus about 10 to 20 degrees, so as tobe certain to only contact hot fluidizing media.

The hot fluidized vaporizing media is a combination of the preferred gasdispersion media and hot circulating solid particles 36 from controlvalve 10. Downstream of the mixing point of these two materials in apremix downcomer 18, dispersion grid 38 in the vaporizing media inlet atthe top of the "top hat" portion 33 of stripper-heater 6 channels thetotal vaporizing media into a flat vertical pattern 39, which willtraverse the flat horizontal pattern 41 of the atomized charge atapproximately 90 degrees. Thus, there is provided a means forintroducing the hot vaporizing media into the contacting zone whichincludes the premix downcomer 18 and dispersion grid 38. The dispersionmedia will actually act to propel the hot fluidizing solid 36 throughdispersion grid 38 with a resultant velocity of less than 40 fps in tophat 33, as discussed previously. The result of mixing these streams inthe contacting zone 27 will be like an explosion as the feed increasesin volume because of vaporization and cracking reaction. This explosionwill result in an acceleration of solid particles mainly throughparticle inlet 30 into the horizontal contactor 26, as this is the onlyway for the vapors to escape. However, some of the non-vaporized charge,which will mainly be asphaltene molecules under going cracking, willform new particles, deposit on the hot circulating fluidizable solid, ordeposit on the solids in the feed. The heavier particles that are notentrained into the horizontal contactor 26 will settle out onto the topof the particulate bed 43 in stripper-heater 6. FIG. 2 depicts by dottedlines the assumed path of the feed and vaporizing media through thecontactor into the inlet to the separator means. If there is more thanone feed point and/or more than one contactor, the dispersion grid 38can be designed to distribute the vaporizing media in another pattern toinsure intimate contact of feed and vaporizing media.

It is important to note that if the molar rate of dispersion media isthe same as the molar rate of the charge vapors after vaporization andreaction, then the resultant velocity of the two in top hat 33 will betwice the velocity of only the dispersion media. In this case, it wouldbe less than 80 fps or the same as the inlet velocity of cyclone 28.Therefore, one can obtain lower contactor times in this type ofapparatus compared to those systems known in the art and using similarequipment. In a 50,000 bpd system, the top hat 33 and horizontalcontactor 26 would be about 45 inches in diameter. The stripper-heater 6diameter would be about 8 feet. If it is assumed that the cyclone 28inlet can be placed right outside the stripper heater 6 vessel wall,then the total length of the contactor 26 from the center of top hat 33is the radius of stripper-heater 6, or 4 feet. At 80 fps the contactortime would be 0.05 seconds. This is ultra-short compared to what isknown in the art. Times this short are impossible in the verticle,folded, or downflow riser contactors/reactors previously discussed inthe art.

The contact time can be increased significantly by increasing thedispersion media flow (top hat velocity increase) and injecting the feeddownwardly into the stripper-heater 6 with the vaporizing mediasurrounding the feed injector. Of course, the length of horizontalcontactor 26 can be increased to increase the contact time.

Compared to either an upflow or downflow vertical riser, the presentsystem has the distinct advantage of a feed injection system thateliminates the possibility of coking problems in the system. A confinedriser is plagued with coking problems because of poor feed andvaporizing media distribution, which results from erratic mediacirculation, insufficient media circulation to vaporize the feed, rapidfeed rate changes, or plugged feed injectors, which results in liquidfeed contacting the confining walls of the riser or feed injector sidesand forming coke. Once the coke forms it continues to grow until therefiner is forced to shutdown the unit. The horizontal contactor isemployed in the present invention not only to minimize the contact timerelative to that in a vertical riser, but also to eliminate the cokingproblems. If override control 20 does not function, the system willcontinue to operate, since the feed injected into the top hat 33 ofstripper-heater 6 will flow downwardly countercurrent to the vapors fromthe bed, which will vaporize the lighter material in the feed. Theremaining unvaporized hydrocarbon, which will be the majority of theheavy carbonaceous material in the feed, will be dispersed on top of theparticulate level (bed) 43 in stripper-heater 6, which will be hotenough to vaporize the feed, since slide valve 40 will open to controlthe level in dipleg surge pot 78, and add the same amount of vaporizingmedia-to the bed level in stripper-heater 6 as was added to the uppersection before losing the vaporizing media flow. In effect, theoperation in this mode will result in a operation approaching a fluidcoking process with the products being highly degraded.

The temperature of the charge-stock in conduit 22 is typically above400° F., and more preferably above 500° F., the charge-stock can bedispersed/atomized with steam, gas, water or by viscosity/differentialpressure control across the feed injector 32. The vaporizing media alongwith the dispersion media contacts the feed and vaporizes the 1000° F.minus and thermally stable molecules boiling above 1000° F. in thehydrocarbon feed with little or no conversion in the ultra-short contacttime contactor 26. The heavy, thermally unstable molecules boiling above1000° F. convert to lighter hydrocarbons, and the high molecularweight/high boiling asphaltene molecules form carbonaceous particles ordeposits on the particles of vaporizing media and decompose into a lowhydrogen solid carbonaceous material and a lighter hydrocarbon product.The hydrocarbon vapors, along with the entrained solid particles, exithorizontal contactor 26 and enter primary contactor cyclones 28 where90% of the entrained solids are separated from the vapors. Thehydrocarbon vapors exit cyclone 28 and are reheated at least 5° F. bythe addition of hot combustor product through slide valve 42 in dip leg82 connected to secondary cyclone 80. This addition, or reheating, ofthe vapors eliminates coking in the high efficiency secondary contactorcyclones 14, where the remaining solids of greater than 10 microns areseparated from the vapors.

The vapors exit secondary cyclone 14 through vapor recovery line 44 andare immediately quenched by introducing a suitable quenching mediathrough line 23 before product separation in distillation equipment (notshown), as is well known in the art. The solids separated in contactorcyclones 28 and 14 enter stripper-heater 6 below the normal particulatelevel 43 in order to seal the diplegs 46 and 48. These particles alongwith the ones which separate from the dispersion media and charge in thestripper-heater top hat 33 are mixed with hot material from thecombustor 4 which enters near the top of the normal particulate level 43of stripper-heater 6 through slide valve 40 in line 45 connected todipleg surge pot 78. The purpose of this hot material is two-fold. Oneis to aid the gas or steam stripping media which enters the bottom ofstripper-heater 6 through line 50 distributor 51 in the stripping andvaporizing of any hydrocarbon liquid that remains on the cold particlesfrom the contactor. The other is to raise the temperature of theparticles to aid in burning of the carbonaceous material in thecombustor 4. Since the combustor 4 is a completely fluidized system, onemust be concerned with the time-temperature relationship, or thekinetics of burning. Therefore, this hot material is added to thestripper-heater 6 at a rate to control the carbon burning rate in thecombustor. This recycle rate can be as high as three times thevaporizing media rate.

It is realized that in the feed atomization-vaporizing media contactingsection 27 of this process that some particles larger than those derivedwill form from agglomeration of the solids in the feed with asphaltenemolecules, by agglomeration with colloidal material in the feed, andlarger than desired carbonaceous/metals products. These particles willnot enter the horizontal contactor 26 with the vaporized feed and themajority of the particles, but will be propelled downwardly onto level43 by the vertical force created by the dispersion gas intersecting theatomized feed at less than 40 fps and their own mass. These particleswill flow downwardly through stripper-heater 6 and mix with the hotmaterial, the particles separated from the product vapors, and thestripping media. The heated particles exit the stripper-heater 6 onlevel control through slide valve 52 in line 53 connecting thestripper-heater 6 and the combustor and enter the combustor bottom 3,which is shown as having a larger diameter than the upper portion ofcombustor 4. This combustor bottom 3 serves two purposes. One is toseparate higher density and larger particles by velocity differences(elutriation). These heavier particles and larger particles will settleor stay in the bottom portion 3 wherein the velocity is lower. They willremain here until they form smaller particles by burning off thecarbonaceous material or by attrition. In essence, this design sizes theparticles for proper fluidization. The smaller particles escape thesystem through the cyclones while the larger particles formed in thecontactor flow by gravity into the combustor bottom 3, where they remainuntil they are the proper size and density for fluidization out of thecombustor bottom into the upper portion of combustor 4. The combustorbottom 3 is instrumentated to indicate the density of the particles atintervals across its height. As the larger, higher density particlesincrease in the lower combustor bottom 3, they are removed through line54 into elutriator-burner 56 before being withdrawn through line 58.

The elutriator-burner 56 includes a conduit wherein the particles aremixed with a source of oxygen, such as air, and is designed to take theheavier particles from the lower combustor 3 to further oxidation ortreating as required. As shown, the present system can be fluidized withair from blower 60 through flow control valve 62. In this way all thecarbon is burned from the particles so that the remaining material whichwould normally be the metals in the feed, plus any heavy feed particles,can be removed through line 58 to disposal or metals recovery. The sizeof elutiator-burner 56 will depend on the amount of total ash in thefeed. The outlet of elutriator-burner 56 can go to any convenientlocation in upper combustor 4 and the elutriator-burner system 56 can beoperated as a batch system if desired.

The second purpose of the increased diameter lower combustor 3 is totrade time for length of the combustor. The typical design conditionsfor the combustor would be less than 20 seconds gas time with apreferred time of 10 seconds at temperatures greater than 1400° F. Thehigher the temperature, the less the time required, so the increasedtime in the lower combustor may at times be unnecessary. In this case,the upper portion of combustor 4 and lower combustor portion 3 would bethe same diameter and the elutriation would take place in anothervessel.

Because this embodiment of the present invention employs a completelyfluidized combustor, it is critical to maintain the velocity in thecombustor within certain ranges. If the velocity is too low theparticles will not be fluidized and the system will stop circulating. Ifthe velocity is too high there will not be enough time to burn thecarbonaceous material formed in the contactor. Therefore, this system isdistinctive in that it recycles flue gas, after cooling, through line 64and startup air from blower 60 through heater 66 into the bottom 3 ofthe combustor through the distributor 68 to fluidize the particulatesentering through slide valve 52 from the stripper-heater 6. The flue gascan be replaced or is normally supplemented with air from air blower 60to obtain the necessary oxygen for combustion. The air blower 60 flowrate is controlled by the inventory in the combustor and the total airplus flue gas flow rate is controlled by flow controller 72. The aircould be replaced with oxygen if there is an air plant available. Thetotal gas rate to the combustor 4 is controlled to give a velocity ofless than 30 fps and normally about 10 fps, but always above thetransport velocity of the carbonaceous particles of the desired size.The fluidized particles, along with the combustion products, continue upthe upper portion of combustor 4 and pass thru line 73 to primarycombustor cyclone 74 where 90%+of the particles are separated from thecombustor gases. The separated particles exit cyclone 74 through dipleg76 to the lower portion of dipleg surge hopper 78, which is used tostrip with steam as much of the flue gas as possible from the hotparticulates to minimize the flue gas carried over to the horizontalcontactor section. The extremely low pore volume of the carbonaceousparticles is also very helpful in reducing the amount of entrained gasesor vapors circulated between vessels. Both primary cyclone 74 andsecondary cyclone 80 diplegs 76 and 82, respectively, discharge belowthe particulate level in surge hopper 78.

The products of combustion, plus some solids, exit primary cyclone 74through line 75 and pass through flue gas cooler 84 before entering highefficiency cyclone 80 where all particles greater than 10 microns areremoved so that the system gases can go to a power recovery system (notshown) without further separation. Also, if the exit gases (flue gas) influe gas line 86 are to be treated downstream for SO_(x) or NO_(x)control, the amount of particles carried over will be minimal.

The flue gas cooler 84 is another unique feature of this process system.In the preferred arrangement, cyclone 80 is not a conventional cold wallcyclone with minimum metal internals exposed to the high temperatures asis primary cyclone 74, but it is a high efficiency cyclone system madeup of multiclones, as in the Euripos third stage cyclone described inU.S. Pat. No. 4,348,215, which may have a temperature limit of less than1600° F. This in many cases is less than the operating temperaturecontemplated for the present process. Therefore, cooling of this streamis provided to protect the multiclones. The preferred method of coolingis a heat exchanger, usually used to produce steam to lower the flue gastemperature to the 1400° F.-1600° F. This exchanger could be replacedwith a liquid or steam quench, but this would normally cause problemsbecause of dew point in downstream equipment.

The pressure on the combustor system is controlled by differentialpressure controller 88, connected to flue gas line 86 and to line 44which passes the contactor vapors to vapor recovery and productseparation. Pressure controller 88 regulates the rate of flue gasesexiting the system through line 86 by adjusting valve 87. Controller 88regulates the pressure differential between the combustor and thecontactor in order to stabilize the particulate circulation.

The control system of this process is unique in that all thecarbonaceous material formed in the contactor must be burned so thatthere is no excess for withdrawal and one does not run out of inventory.It is a balance of inventory and oxygen demand. Therefore, all theparticulate levels in the combustor 4, including lower combustor portion3, the stripper-heater 6, and the dipleg surge pot 78 are monitoredcontinually. The particulate level/inventory in the combustor 3/4 is theonly system not on control and therefore is really the only variable oninventory. As a minimum, the oxygen rate is reset by the change ininventory in the combustor. That is, if the combustor inventoryincreases, the air flow rate to the combustor is increased to burn moreof the carbonaceous particles and decrease the inventory. If theinventory decreases, the opposite happens and the air flow rate throughair blower 60, or the oxygen rate, is decreased and the burningdecreased. Of course, the exact opposite happens to the recycled fluegas since the total gas rate to the combustor is controlled by flowcontroller 72. If one needs to minimize the amount of CO in the flue gasline 86, the combustor flue gas temperature should be a minimum of 1400°F.

Depending upon the contaminants in the charge-stock, it may beadvantageous to initially add finely divided particles of charcoal, clayor the like to the charge fed to the above-described system to initiatethe formation of circulating particles, but such additions are stoppedonce adequate particles are formed. If clay, or another such noncombustible solid is used, it is withdrawn from the system through line58 as described above.

Principal differences between the system of the present invention andfluid coking or the selective vaporization processes are:

The system of the present invention employs a downwardvaporizing-dispersion media flow followed by an essentially horizontalfeed injection and horizontal contactor. This eliminates coking in theequipment and results in much shorter contact times between thevaporized charge and the hot solid particles than can be accomplished inknown systems. Not counting contact time in the cyclone section, whichcan be as high as 0.5 seconds, this system can provide contact times offrom about 0.1 to about 0.2 seconds.

The present system employs a stripper-heater for minimizing hydrocarbonproduct entrainment into the combustor, and also for increasing thecontactor particle temperature to decrease the time necessary forcombustion.

The air rate to the combustor is controlled on inventory.

The combustor is a completely fluidized system with flue gas recycle tomaintain the desired velocity in the combustor.

The use of a flue gas cooler between the primary and secondary cycloneson the combustor.

The use of a dipleg surge pot as a stripper to reduce gas carryover tothe horizontal contactor.

Injecting the hot combustor particles into the stripper-heater at thetop of the particulate level therein to increase the temperature of thevapors leaving the particulate bed in the stripper-heater to eliminatecoking which might result from contacting cooler stripping vapors withheavy hydrocarbon vapors.

Using the bottom combustor as a lower velocity elutriator.

The process self-generates the particulates from the feedstock but onlygenerates enough for heat balance. Therefore, there it is not necessaryto withdraw any coke material from the system.

Having described the principles and a preferred embodiment of thepresent invention, it should be recognized that modifications andvariations thereof falling within the scope of the appended claims willbecome apparent to one skilled in the art.

What is claimed is:
 1. Apparatus for the treatment of a liquidhydrocarbon charge containing solids or solids-forming contaminantscomprising:(a) a contactor vessel having at least one liquid chargeinlet, at least one vaporizing media inlet above said charge inlet andat least one vapor-solids outlet; (b) atomizing means positioned in saidcharge inlet for forming small particles of said liquid charge having apreselected size and directing said particles of liquid substantiallyhorizontally into said contactor vessel; (c) vaporizing mediaintroduction means positioned in said vaporizing media inlet forintroducing a fluidized mixture of a gas dispersion media and hotcirculating solid particles into said contactor vessel substantiallyvertically so as to traverse the path of said liquid particles andintimately contact said liquid particles; and (d) contactor separatormeans connected to said vapor-solids outlet for separating solidparticles entrained in vapors formed in said contactor vessel; (e)wherein said vapor-solids outlet is positioned in said contactor vesselsubstantially opposite said liquid charge inlet to receive said vaporsand entrained solid particles and rapidly pass the same into saidseparator means.
 2. The apparatus of claim 1, further including astripper vessel beneath and in flow communication with said contactorvessel for receiving heavy solid particles from said contactor vesseland stripping hydrocarbons from said solid particles.
 3. The apparatusof claim 1, further including a combustor vessel interconnected withsaid stripper vessel for receiving stripped solid particles therefrom,means for fluidizing solid particles in said combustor vessel and forburning carbonaceous material from said solid particles therein, andfirst conduit means for passing the burned solid particles to saidvaporizing media inlet.
 4. The apparatus of claim 3, wherein saidcombustor vessel has an upper portion and a lower portion and whereinsaid lower portion has a larger diameter than said upper portion.
 5. Theapparatus of claim 4, further including withdrawing means connected tosaid lower portion for withdrawing therefrom solid particles heavierthan that which is fluidized in said combustor vessel.
 6. The apparatusof claim 5, further including elutriator-burner means connected to saidwithdrawing means for further burning solid particles withdrawn fromsaid lower portion.
 7. The apparatus of claim 3, wherein said contactorseparator means comprises primary and secondary separators, the primaryseparator having a vapor outlet and the secondary separator having aninlet interconnected with said primary separator vapor outlet, andfurther including means for adding hot burned solid particles from saidcombustor vessel to vapors passed from said primary separator vaporoutlet to the inlet of said secondary separator to raise the temperatureof the vapors.
 8. The apparatus of claim 7, further including thirdconduit means for passing separated solids from said contactor separatormeans into said stripper vessel.
 9. The apparatus of claim 3, furtherincluding multiple-stage combustor separation means connected to saidfirst conduit means for separating burned solid particles fromcombustion products produced in said combustor vessel by said burning ofcarbonaceous material.
 10. The apparatus of claim 9, further includingsecond conduit means for passing separated burned solid particles fromsaid multiple-stage combustor separation means into said strippervessel.
 11. The apparatus of claim 9, further including cooling meansbetween the stages of said combustor separation means for cooling theproducts of combustion passed through said combustor separator means.12. The apparatus of claim 3, wherein said combustor vessel has an upperportion and a lower portion, and further including (1) combustorseparation means connected to said upper portion of said combustorvessel for separating burned solid particles from combustion productsproduced in said combustor vessel by said burning of carbonaceousmaterials and (2) means for passing separation combustion products fromsaid combustor separation means to said lower portion of said combustorvessel.
 13. The apparatus of claim 12, further including means forintroducing an oxygen-containing gas into said lower portion of saidcombustor vessel.
 14. The apparatus of claim 13, further including meansfor controlling the flow rates of said separated combustion products andsaid oxygen-containing gas introduced into said lower portion of saidcombustor vessel.
 15. The apparatus of claim 1, further including atemperature sensing element and first flow measuring device in saidvaporizing media introduction means, a charge conduit connected to saidatomizing means, a second flow measuring device connected to said chargeconduit, a valve in said charge conduit and a computer connected to saidtemperature sensing element and said first and second flow measuringdevices for receiving signals therefrom and connected to said valve forsending signals thereto so as to control the flow rate of charge throughsaid charge conduit in response to the signals received.
 16. Theapparatus of claim 1, wherein said vaporizing media introduction meanscomprises a premix downcomer having a dispersion grid positionedtherein, for channeling the vaporizing media downwardly in asubstantially flat vertical pattern.
 17. The apparatus of claim 16,wherein said atomizing means is provided with an orifice for forming asubstantially flat horizontal pattern of said particles of liquid.